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- W2089899110 abstract "The syntheses of the cyclic N-phosphino-amidines and -guanidines Ph2PN(Pri)C(NPri2)N(Pri) (1) and Ph2PN(c-Hex)C(R)N(c-Hex) [R = piperazino (2), morpholino (3), Me (4), and Ph (5)] are reported. DFT studies have identified the preferred structures for compounds 1–5 with the E-configuration being the most stable form for the N-phosphino-amidines, while the Z-conformation is preferred for the N-phosphino-guanidines something that highlights the potential of such systems to act as κ2-P,N-chelates. The differences in donor characteristics of 2–5 have been probed through the study of their corresponding P(V) selenide derivatives (6–9) and their complexes with the cis-RhCl(CO) (10–12) and cis-PdCl2 (13–17) fragments. In line with the DFT studies both the amidines and guanidines are found to coordinate as κ2-P,N-chelates, with the latter being moderately weaker donor ligands. The molecular structures of compounds 3 and 4, together with those of the Rh and Pd complexes 10 and 15, respectively, have been determined in the solid state by X-ray crystallography, the latter confirming bidentate κ2-P,N-chelation." @default.
- W2089899110 created "2016-06-24" @default.
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- W2089899110 date "2008-01-01" @default.
- W2089899110 modified "2023-10-17" @default.
- W2089899110 title "N-Phosphino-amidines and -guanidines: synthesis, structure and P,N-chelate chemistry" @default.
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- W2089899110 doi "https://doi.org/10.1039/b715736c" @default.
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