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• W2089904239 abstract "The hydrogen absorption pressure-composition-isotherms of the PuNi3 type rhombohedral Tb1−xZrxFe3 (x=0.1, 0.2, 0.3) alloys are investigated by Sievert’s apparatus, in the temperature and pressure ranges 75≤T(°C)≤150 and 0.1≤P(bar)≤25, respectively, with a view to study the dependence of hydrogen solubility and the plateau pressure on Zr content. The P-C isotherms show the presence of a single plateau region in the temperature and pressure ranges studied and it is found that the plateau pressure at any given temperature increases with increase of Zr content along with a reduction in the hydrogen capacity. The absorption of hydrogen is accompanied by a maximum of 17.4% expansion in the unit cell volume of the host material without any change in PuNi3 type structure as evidenced by the X-ray diffraction studies on the alloy– hydrides. The presence of single and two phase regions as seen in the P-C isotherms are confirmed from the powder X-ray diffractogram of the alloy–hydrides with appropriate hydrogen concentration. The powder X-ray diffractograms on the alloy–hydrides with maximum hydrogen concentration further show the absence of hydrogen induced amorphization (H1A) upon hydrogenation." @default.
• W2089904239 created "2016-06-24" @default.
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• W2089904239 date "1999-06-01" @default.
• W2089904239 modified "2023-10-16" @default.
• W2089904239 title "Hydrogen absorption characteristics in the Tb1−xZrxFe3 (x=0.1, 0.2, 0.3) system" @default.
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• W2089904239 doi "https://doi.org/10.1016/s0925-8388(98)01044-5" @default.
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