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- W2089922204 abstract "We examine, with the aid of a much simplified model, the competition between π-electron delocalization energy and chain conformation entropy that occurs when a conjugated polymer is placed in solution. For a lightly doped π-band we predict the existence of conformons, i.e. locally rigid regions, each containing one or more π-electrons, on an otherwise flexible chain. We also consider the case of a half-filled band, and in this case find that the freezing out of chain degrees of freedom can contribute significantly to the sharpness of a rod-to-coil transition." @default.
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- W2089922204 date "1987-07-01" @default.
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- W2089922204 title "“Conformons”: Self-Localized Electrons in Soluble Conjugated Polymers" @default.
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- W2089922204 doi "https://doi.org/10.1209/0295-5075/4/1/007" @default.
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