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- W2089931992 abstract "Epoxidation of Carbon-Carbon Double Bonds in Terpenes by Linoleic Acid Hydroperoxides Epoxidation of CC double bonds in terpenes is achieved by reaction with linoleic acid hydroperoxides (LOOH) exemplified with caryophyllene (3), methyl farnesoate (5) and squalene (8). Linoleic acid (9S)-hydroperoxide was obtained by reaction of linoleic acid (1) with lipoxygenase present in tomato homogenisate. When 18O2-labeled (9S)-LOOH (2) was used 18O was found in the terpene epoxide. While 3 is converted under physiological conditions regioselectively in high yiled into its 4,5-epoxide 4, the yield of epoxidized products from long-chain molecules, e.g. squalene (8), decreases strongly and no regioselectivity was observed." @default.
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- W2089931992 date "1993-12-13" @default.
- W2089931992 modified "2023-10-16" @default.
- W2089931992 title "Epoxidierung von Kohlenstoff-Kohlenstoff-Doppelbindungen in Terpenen durch Linolsäurehydroperoxide" @default.
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- W2089931992 doi "https://doi.org/10.1002/jlac.1993199301204" @default.
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