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- W2089942070 abstract "The complex (dmp)CuI(BH4) with dmp=2,9-dimethyl-1,10-phenanthroline displays a long-wavelength absorption at λmax=465nm which is assigned to a BH4−→dmp ligand-to-ligand charge transfer (LLCT) transition. In the solid state the LLCT state is emissive (λmax=626nm). In non-coordinating solvents such as CH2Cl2,CHCl3 or toluene the complex undergoes a photoredox decomposition leading to the generation of metallic copper. At λirr=436nm(dmp)CuI(BH4) disappears with φ=1.2×10−3." @default.
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- W2089942070 date "2002-04-01" @default.
- W2089942070 modified "2023-10-06" @default.
- W2089942070 title "Photoreactivity of (2,9-dimethyl-1,10-phenanthroline) copper(I) borohydride" @default.
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- W2089942070 doi "https://doi.org/10.1016/s1387-7003(02)00349-0" @default.
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