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- W2089963868 abstract "Near steady-state photoinduced absorption (PIA) and UV-Vis absorption spectroscopy are used to characterize the pore filling of spiro-MeOTAD (<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mn>2</mml:mn><mml:mo>,</mml:mo><mml:msup><mml:mn>2</mml:mn><mml:mo>′</mml:mo></mml:msup></mml:math>,<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mn>7</mml:mn><mml:mo>,</mml:mo><mml:msup><mml:mn>7</mml:mn><mml:mo>′</mml:mo></mml:msup></mml:math>-tetrakis-(<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>N</mml:mi><mml:mo>,</mml:mo><mml:mi>N</mml:mi></mml:mrow></mml:math>-di-<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mi>p</mml:mi></mml:math>-methoxyphenylamine)<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mn>9</mml:mn><mml:mo>,</mml:mo><mml:msup><mml:mn>9</mml:mn><mml:mo>′</mml:mo></mml:msup></mml:math>-spirobifluorene) into the nanoparticulate TiO 2 electrode of a solid-state dye-sensitized solar cell (ssDSC). The volumetric ratio of filled to unfilled pore volumes, as well as the optical signature of interacting chemical species, that is, the hole-transfer yield (HTY), are investigated. PIA spectroscopy is used to measure the HTY, relative to the amount of spiro-MeOTAD present, without needing to determine the extinction coefficients of the dye and spiro-MeOTAD cation species. The Beer-Lambert law is used to relate the relative PIA signal to the penetration length of the hole-conductor in the TiO 2 film. For the sample thickness range of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mn>1.4</mml:mn><mml:mtext>–</mml:mtext><mml:mn>5</mml:mn></mml:math> μ m investigated here, the optimum characteristic penetration length is determined to be<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mn>3.1</mml:mn><mml:mo>+</mml:mo><mml:mn>0.46</mml:mn></mml:math> μ m, which is compared to 1.4 μ m for the 200 mg<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:msup><mml:mtext>mL</mml:mtext><mml:mrow><mml:mo>−</mml:mo><mml:mn>1</mml:mn></mml:mrow></mml:msup></mml:math>concentration of spiro-MeOTAD conventionally used. Therefore, doubling the effective penetration of spiro-MeOTAD is necessary to functionalize all the dye molecules in a ssDSC." @default.
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- W2089963868 date "2011-01-01" @default.
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- W2089963868 title "Characterization of the Pore Filling of Solid State Dye Sensitized Solar Cells with Photoinduced Absorption Spectroscopy" @default.
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