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- W2089969139 abstract "The evidence for the d8 carbonyl—nitrosyl Cr(CO)3(NO)2 is re-examined. Making use of ligand effect constants, to calculate energy-factored force constants and ν(CO) frequencies, we conclude that Cr(CO)3(NO)2 does not have the D3h structure suggested by Satija et al. [Inorg. Chem. 17, 1737 (1978)]. We find that it has a C2v structure, with the NO groups occupying two equatorial positions of a trigonal bipyramid. The hitherto unidentified complex Cr(CO)4(NO), which was formed in low yield in Satija et al.'s experiments, appears to have a C4v structure that is very similar to the isoelectronic molecule Mn(CO)5." @default.
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- W2089969139 date "1992-07-01" @default.
- W2089969139 modified "2023-10-16" @default.
- W2089969139 title "Infrared spectral evidence for tricarbonyldinitrosylchromium, Cr(CO)3(NO)2—A re-examination" @default.
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- W2089969139 doi "https://doi.org/10.1016/0584-8539(92)80171-r" @default.
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