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- W2089969328 abstract "Compounds having two benzocrown ether units bridged by a mono-, di-, or trisilanylene unit were prepared, and ionochromic effects on their optical properties were studied. Of these, disilanylene- and trisilanylene-bridged ones exhibited clear ionochromism in the emission spectra and the intensity of the original emission band at about 320 nm decreased and a new broad band centered at 400 nm appeared when appropriate alkali or alkali-earth metal ions were added into the acetonitrile solutions. In contrast, a monosilanylene-bridged benzocrown ether and a disilanylbenzocrown ether showed ionochromic changes in different fashions, indicating that the new emission band at low energy of the di- and trisilanylene-bridged benzocrown ethers in the presence of metal ions may be ascribed to the intramolecular π−π stacking. MO calculations were carried out to understand the ionochromism." @default.
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- W2089969328 date "2005-04-29" @default.
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- W2089969328 title "Synthesis of Silicon-Bridged Benzocrown Ethers and Their Ionochromism in the Emission Spectra Arising from Intramolecular π−π Stacking" @default.
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- W2089969328 doi "https://doi.org/10.1021/om0400907" @default.
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