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- W2089979105 abstract "cis-Oligo(phenylenevinylene)s (OPVs) are synthesized by Suzuki−Miyaura coupling of arylboronic acids with (Z)-bromoalkenes in over 96% geometrical purity. On the other hand, trans-oligo(phenylenevinylene)s can be synthesized by Hiyama coupling of aryl iodide with (E)-alkenylsilanes in almost perfect purities. Effect of π-conjugation chain length on photoisomerization behavior of OPVs is described." @default.
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- W2089979105 date "2006-03-07" @default.
- W2089979105 modified "2023-10-03" @default.
- W2089979105 title "Stereoselective Synthesis of <i>cis</i>- and <i>trans</i>-Oligo(phenylenevinylene)s via Palladium-Catalyzed Cross-Coupling Reactions" @default.
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- W2089979105 doi "https://doi.org/10.1021/jo052602c" @default.
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