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- W2090045271 abstract "Abstract The enthalpies of solution of 1,3-dimethylpropyleneurea in ordinary (H 2 O) and heavy (D 2 O) water were measured at (278.15, 283.15, 288.15, 298.15, and 313.15) K and atmospheric pressure. Standard enthalpies and heat capacities of solution (hydration), along with D 2 O–H 2 O solvent isotope effects on the quantities studied, were computed. The enthalpies of solution as well as corresponding solvent isotope effects were found to be negative and decreasing in magnitude with increasing temperature. It was established that the hydration (mainly of a hydrophobic type) is enhanced in D 2 O and on going from 1,3-dimethylethyleneurea (1,1,3,3-tetramethylurea) to 1,3-dimethylpropyleneurea, whereas the enthalpy-isotope effects become less appreciable in the latter case." @default.
- W2090045271 created "2016-06-24" @default.
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- W2090045271 date "2011-02-01" @default.
- W2090045271 modified "2023-09-25" @default.
- W2090045271 title "D2O–H2O solvent isotope effects on the enthalpy of 1,3-dimethylpropyleneurea hydration at temperatures from (278.15 to 313.15)K and atmospheric pressure" @default.
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- W2090045271 doi "https://doi.org/10.1016/j.tca.2010.11.025" @default.
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