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• W2090064364 abstract "Time resolved studies of silylene, SiH2, generated by the 193 nm laser flash photolysis of phenylsilane, have been carried out to obtain rate coefficients for its bimolecular reactions with methyl-, dimethyl- and trimethyl-silanes in the gas phase. The reactions were studied over the pressure range 3–100 Torr with SF6 as bath gas and at five temperatures in the range 300–625 K. Only slight pressure dependences were found for SiH2 + MeSiH3 (485 and 602 K) and for SiH2 + Me2SiH2 (600 K). The high pressure rate constants gave the following Arrhenius parameters:" @default.
• W2090064364 created "2016-06-24" @default.
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• W2090064364 date "2007-01-01" @default.
• W2090064364 modified "2023-10-16" @default.
• W2090064364 title "Gas phase kinetic and quantum chemical studies of the reactions of silylene with the methylsilanes. Absolute rate constants, temperature dependences, RRKM modelling and potential energy surfaces" @default.
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• W2090064364 doi "https://doi.org/10.1039/b613638a" @default.
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