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- W2090091768 abstract "The migration of hydrogen in metals plays an important role in many fields of science and technology. Secondary ion mass spectrometry (SIMS) is a suitable method for analysis of hydrogen in solids, but there are still unsolved problems (sputter enhanced migration, stable reference materials for quantification). The complex process of the migration of hydrogen and the secondary H+ ion emission from a homogeneous solid matrix (Zr50Ni25Cu25 amorphous alloy) of high H-concentration (H/Me atomic ratio up to 0.9) was studied. A kinetic model for consecutive diffusion and sputtering-enhanced desorption processes was set up. Sputtering-influenced and long-time (months) experiments were carried out for the study of hydrogen storage and outgassing of amorphous alloys. Rate constants for ion induced desorption and outgassing, and the activation energy for diffusion, were calculated. © 1998 John Wiley & Sons, Ltd." @default.
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- W2090091768 date "1998-10-30" @default.
- W2090091768 modified "2023-09-24" @default.
- W2090091768 title "Hydrogen outgassing of ZrNiCu(H) amorphous alloy studied by secondary ion mass spectrometry" @default.
- W2090091768 doi "https://doi.org/10.1002/(sici)1097-0231(19981030)12:20<1510::aid-rcm334>3.0.co;2-2" @default.
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