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- W2090168265 abstract "The ion pair collapse versus radical pair collapse hypothesis is proposed for the Grignard reagent formation as an extension of the e.t. mechanism of aromatic nitration. Such a scheme, never examined before for the Grignard reaction, could explain the evolution of the ‘free radical character’ depending on experimental conditions and the nature of the substrate. L’hypothèse ion pair collapse/radical pair collapse est proposée ici pour la formation de réactifs de Grignard comme une extension du mécanisme de nitration aromatique par transfert d’électrons. Un tel schéma, jamais envisagé jusqu’à maintenant pour la réaction de Grignard, pourrait expliquer l’évolution du « caractère radicalaire » en fonction de la nature de l’halogénure, du solvant et de certains effets de sel." @default.
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- W2090168265 date "2001-07-01" @default.
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- W2090168265 title "Extension of the e.t. mechanism of aromatic nitration to the formation of Grignard reagents of RX (R = alkyl, aryl, cyclopropyl, vinyl). The ion pair collapse versus radical pair collapse hypothesis" @default.
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- W2090168265 doi "https://doi.org/10.1016/s1387-1609(01)01268-3" @default.
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