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- W2090195874 abstract "The laser induced fluorescence spectrum of palladium dimer (Pd2) in the visible region between 480 and 700 nm has been observed and analyzed. The gas-phase Pd2 molecule was produced by laser ablation of palladium metal rod. Eleven vibrational bands were observed and assigned to the [17.1]${}^3Pi _g - X{}^3Sigma _u^ +$Πg3−XΣu+3 transition system. The bond length (ro) and vibrational frequency (ΔG1/2) of the ground $X{}^3Sigma _u^ +$XΣu+3 state were determined to be 2.47(4) Å and 211.4(5) cm−1, respectively. A molecular orbital energy level diagram was used to understand the observed ground and excited electronic states. This is the first gas-phase experimental investigation of the electronic transitions of Pd2." @default.
- W2090195874 created "2016-06-24" @default.
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- W2090195874 date "2013-11-15" @default.
- W2090195874 modified "2023-10-01" @default.
- W2090195874 title "Electronic transitions of palladium dimer" @default.
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- W2090195874 doi "https://doi.org/10.1063/1.4829767" @default.
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