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• W2090298453 abstract "Cleavage of adenosine-5′-monophosphate (5′-AMP), guanosine-5′-monophosphate (5′-GMP), adenosine-3′-monophosphate (3′-AMP) and guanosine-3′-monophosphate (3′-GMP) by lanthanides was investigated by NMR and the method of measuring the liberated phosphates. Rapid cleavage of both 5′-mononucleotides and 3′-mononucleotides by CeIII and CeIV under air at pH 9 and 37°C was observed. Other lanthanides showed less efficiency for hydrolyzing 5′-mononucleotides but 3′-mononucleotides were catalyzed by a range of lanthanide ions. The mechanism for hydrolyzing 3′-mononucleotides by lanthanides was investigated. The notable difference in reactivity between CeIII and the other lanthanide ions under air was further studied showing that the cleavage is enhanced with increasing molar fraction of CeIV. The fast cleavage of mononucleotides by CeIII under air at pH 9 is ascribed to the resultant CeIV in the reaction mixture." @default.
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• W2090298453 date "1997-01-01" @default.
• W2090298453 modified "2023-10-17" @default.
• W2090298453 title "Lanthanide ions for the hydrolysis of 5′-mononucleotides and 3′-mononucleotides" @default.
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• W2090298453 doi "https://doi.org/10.1016/s0277-5387(97)00082-x" @default.
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