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- W2090352010 abstract "Perfluoroalkenylmagnesium bromides RFCFCFMgBr (RF=C4F9, C6F13), obtained from the corresponding l-bromo-perfluoroalkenes, react with carbonyl compounds to give, with good yields, a series of new α-β unsaturated polyfluorinated alcohols RFCFCFC(OH)(RR′). The synthesis of these compounds is described, and their spectrographic characteristics (IR, 19F and 1H NMR, mass) are reported and discussed. Les bromures de perfluoroalcénylmagnésium RFCFCFMgBr (RF=C4F9, C6F13) préparés à partir des bromo-1 perfluoroalcènes correspondants, reagissent avec les composés carbonylés pour donner, avec de bons rendements, de nouveaux alcools polyfluorés α-β insaturés RFCFCFC (OH)(RR′). La synthèse de ces composés est décrite, et leurs caractéristiques spectrales (IR, RMN du 19F et du 1H, masse) sont présentées et discutées." @default.
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- W2090352010 date "1980-02-01" @default.
- W2090352010 modified "2023-09-23" @default.
- W2090352010 title "Synthese et reactivite d'organomagnesiens perfluores. IV1. Preparation et caracteristiques spectrales de perfluoroalcenyl-carbinols." @default.
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- W2090352010 doi "https://doi.org/10.1016/s0022-1139(00)82587-7" @default.
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