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- W2090390505 abstract "Abstract Monitoring the band of the antisymmetric stretching vibration of the backbone PO2 − group in DNA-anthracycline complexes demonstrates an extraordinary wavenumber shift for the adriamycin complex compared to that of daunomycin. The structures of both anthracyclines, however, are very closely related and differ only by a surplus hydroxyl group of adriamycin in the C14 position. The wavenumber shift observed for the DNA-adriamycin complex is unequivocally attributed to an additional linkage of the C14-OH of adriamycin to the phosphate group of DNA. Thus, serveral of the hypothetical structural models for the DNA-adriamycin complex for which a hydrogen bond between the C14 hydroxyl of the drug and DNA phosphate was postulated (S. Neidle, Cancer Treatment Rep. 61, 928 (1977); G. J. Quigley et. al., Proc. Natl. Acad Sci. USA 77, 7204 (1980)) get the first clear-cut experimental evidence." @default.
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- W2090390505 date "1986-10-01" @default.
- W2090390505 modified "2023-09-25" @default.
- W2090390505 title "Interaction of the C14-OH Group of Adriamycin with DNA Phosphate as Spectroscopically Evidenced" @default.
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- W2090390505 doi "https://doi.org/10.1080/07391102.1986.10506343" @default.
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