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• W2090439063 startingPage "143" @default.
• W2090439063 abstract "The YBa2Fe3O7+x (x = 0.69) compound, synthesized through normal ceramic routes, is found to have an orthorhombic structure (Pmmm, a=3.9078(11), b=3.9406(4), c=11.7292(37)) with Fe3+ occupying two nonequivalent sites (1a and 2q). Mössbauer studies (MES) reveal an AFM order with a Beff that follows a S = 52 Brillouin function, giving Beff(T=0) = (48.5 ± 0.5) T and TN = (1020 ± 10) K. Due to their highly symmetric character, the (6S) Fe3+ ions are insensitive to their surrounding electronic environment, consequently a single set (rather than two sets) of hyperfine parameters, is reflectedf in MES spectra. Based on the above results, as well as on data published, some comments are given regarding the interpretation of the MES results of the much studied YBa2(Cu1−yFey)3O7−z system." @default.
• W2090439063 created "2016-06-24" @default.
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• W2090439063 date "1991-11-01" @default.
• W2090439063 modified "2023-09-28" @default.
• W2090439063 title "Structural and magnetic properties of YBa2Fe3O7+x Fe-based 1-2-3 ceramic oxide" @default.
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• W2090439063 doi "https://doi.org/10.1016/0921-4534(91)90777-v" @default.
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