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• W2090475235 startingPage "387" @default.
• W2090475235 abstract "The structure of wet SiO2 gel before any drying was studied by means of Raman spectroscopy. The vibrational structure of the gel network in water at room temperature already resembles that of bulk vitreous silica. Typical bands formed due to ring breathing of three-membered siloxane rings at 605 cm−1 (D2) and of four-membered siloxane rings at 495 cm−1 (D1) are absent in the Raman spectrum of the unheated gel. As in F-doped fused silica, the sharp, very intense and strongly polarized Raman peak at 490 cm−1, in silica gel, which we label D0, is interpreted as the symmetric stretch oxygen vibration of three network oxygen atoms connected to a silicon atom which has become decoupled from the network via a terminating hydroxyl group." @default.
• W2090475235 created "2016-06-24" @default.
• W2090475235 creator A5024272313 @default.
• W2090475235 creator A5032370589 @default.
• W2090475235 date "1987-09-01" @default.
• W2090475235 modified "2023-09-30" @default.
• W2090475235 title "The origin of the “defect” 490 cm−1 Raman peak in silica gel" @default.
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• W2090475235 doi "https://doi.org/10.1016/s0022-3093(87)80183-7" @default.
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