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- W2090485290 abstract "The electron transfer photo-sensitized reaction of 7-(spirocyclopropane)quadricyclane (1) with methanol produces two rearranged mono-methanol adducts, 2 and 3, and a bis-methanol adduct, 4. The products reveal that 1·+ reacts by stereo- and regiospecific attack of methanol on one trisubstituted cyclopropane ring. The resulting free radical rapidly undergoes one or two (consecutive) cyclopropylcarbinyl to butenyl rearrangements. The mono-adducts are formed by net hydrogen abstraction, the di-adduct via a (secondary) electron transfer reaction of 3. © 1997 John Wiley & Sons, Ltd." @default.
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- W2090485290 date "1997-08-01" @default.
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- W2090485290 title "Electron transfer photochemistry of 7-(spirocyclopropane)quadricyclane: capture of a radical cation and sequential cyclopropylcarbinyl rearrangements" @default.
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- W2090485290 doi "https://doi.org/10.1002/(sici)1099-1395(199708)10:8<607::aid-poc931>3.0.co;2-p" @default.
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