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- W2090531408 abstract "A (phenylenediselenolato)cobalt complex dimer, [Co(eta(5)-C(5)H(5))(Se(2)C(6)H(4))](2) (1), was synthesized by a reaction of carbonyl(eta(5)-cyclopentadienyl)diiodocobalt(III) ([Co(eta(5)-C(5)H(5))I(2)(CO)]) with poly(o-diselenobenzene). The structure of 1, determined by single-crystal X-ray crystallography, was found to be located in the space group of P2(1)/c (No. 14), with a = 9.3346(5) A, b = 11.6477(9) A, c = 10.2179(5) A, beta = 111.491(1) degrees, and Z = 2. Covalent Co-Se bonds bridge the metal centers. In solution, dimers and monomers coexist at equilibrium. The dissociation equilibrium constant of 1 in solution was evaluated by (1)H NMR spectra at several temperatures between 20 and 80 degrees C. Dissociation enthalpies/entropies were found to be 50/110, 60/120, and 88 kJ mol(-1)/200 J K(-1) mol(-1) in dimethyl sulfoxide-d(6), benzene-d(6), and chloroform-d(1), respectively." @default.
- W2090531408 created "2016-06-24" @default.
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- W2090531408 date "2003-02-14" @default.
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- W2090531408 title "Synthesis, Structure, and Dissociation Equilibrium of [Co(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(Se<sub>2</sub>C<sub>6</sub>H<sub>4</sub>)]<sub>2</sub>, a Novel Metalladiselenolene Complex" @default.
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- W2090531408 doi "https://doi.org/10.1021/ic025865n" @default.
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