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- W2090581527 abstract "The solvent extraction of Ti(IV) from sulfate medium by the commercial extractant Cyanex 301 (HA) has been studied in order to examine this novel system. Heptan-1-ol (5% (v/v) in the organic phase) is used as a de-emulsifier. The equilibration time is 45 min. The experimental results suggest that the extracted species is always TiOA2 (o), though the composition of the reacting aqueous Ti(IV) species may vary depending on the concentration levels of Ti(IV), pH, HA and . The equilibrium constant (Kex) at 303 K is measured to be 101.117 and 10−1.243 for the reaction of monomeric, non-sulfated, mono, and non-hydrolyzed TiO2+, respectively. The effects of heptan-1-ol, temperature, loading, and diluent type have been reported. Stripping can be done effectively by a solution of 1 mol/dm3 H2SO4 containing 5%(v/v) of “100 volume” H2O2. The possibilities of separation of Ti(IV) from Cu(II), Zn(II), Fe(III), Co(II), and Ni(II) have been predicted. It is proved to be an effective extractant for Ti(IV)/Fe(III) separat..." @default.
- W2090581527 created "2016-06-24" @default.
- W2090581527 creator A5035011612 @default.
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- W2090581527 date "2014-01-17" @default.
- W2090581527 modified "2023-09-27" @default.
- W2090581527 title "Solvent Extraction of Ti(IV) from Acidic Sulphate Medium by Cyanex 301 Dissolved in Kerosene" @default.
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- W2090581527 doi "https://doi.org/10.1080/01496395.2013.837484" @default.
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