Matches in SemOpenAlex for { <https://semopenalex.org/work/W2090581919> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2090581919 endingPage "596" @default.
- W2090581919 startingPage "591" @default.
- W2090581919 abstract "The dissociation of tris-(2,2'-bipyridyl) iron(II) ([Fe(bipy)3]2+) has been studied in the Triton X-100/hexanol/cyclohexane reverse micellar medium. The reaction obeys simple first-order kinetics with no evidence of autoinhibition. The first-order rate constant (k1) has been determined at different values of W ([H2O]/[Triton X-100]). The rate (k1) decreases with increasing value of W. k1 also increases with increase in Triton X-100 concentration at constant values of W, showing that the reaction takes place at greater speed at the micellar interface. The kinetic results can be interpreted by the monomolecular pseudo-phase model. The effect of W on rate (k1) is more pronounced in the range of W from 1.55 to 4.2 but less pronounced at higher W. The reaction is further accelerated by Cl- and SCN- ions and the kinetic results provide evidence for the formation of ion pairs between the cation [Fe(bipy)3]2+ and each of these anions. The formation of such ion pairs has not been observed in aqueous medium but has been reported earlier in aqueous-alcohol mixtures. This result therefore provides evidence for the lower micropolarity of solubilized water compared to ordinary water." @default.
- W2090581919 created "2016-06-24" @default.
- W2090581919 creator A5000441293 @default.
- W2090581919 creator A5033233389 @default.
- W2090581919 creator A5083871967 @default.
- W2090581919 creator A5085820419 @default.
- W2090581919 date "2005-08-01" @default.
- W2090581919 modified "2023-09-27" @default.
- W2090581919 title "Kinetics of dissociation of tris-(2,2′-bipyridyl) iron(II) in water solubilized by Triton X-100 reverse micelles" @default.
- W2090581919 cites W168596846 @default.
- W2090581919 cites W1914761628 @default.
- W2090581919 cites W1970722438 @default.
- W2090581919 cites W1973829285 @default.
- W2090581919 cites W1983826641 @default.
- W2090581919 cites W1987537801 @default.
- W2090581919 cites W1991502004 @default.
- W2090581919 cites W2007336817 @default.
- W2090581919 cites W2010821458 @default.
- W2090581919 cites W2023772638 @default.
- W2090581919 cites W2036266739 @default.
- W2090581919 cites W2045187131 @default.
- W2090581919 cites W2047693227 @default.
- W2090581919 cites W2053239453 @default.
- W2090581919 cites W2062995276 @default.
- W2090581919 cites W2067007924 @default.
- W2090581919 cites W2074605265 @default.
- W2090581919 cites W2160635072 @default.
- W2090581919 cites W2950378560 @default.
- W2090581919 doi "https://doi.org/10.1016/j.jcis.2005.03.026" @default.
- W2090581919 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15927630" @default.
- W2090581919 hasPublicationYear "2005" @default.
- W2090581919 type Work @default.
- W2090581919 sameAs 2090581919 @default.
- W2090581919 citedByCount "12" @default.
- W2090581919 crossrefType "journal-article" @default.
- W2090581919 hasAuthorship W2090581919A5000441293 @default.
- W2090581919 hasAuthorship W2090581919A5033233389 @default.
- W2090581919 hasAuthorship W2090581919A5083871967 @default.
- W2090581919 hasAuthorship W2090581919A5085820419 @default.
- W2090581919 hasConcept C102931765 @default.
- W2090581919 hasConcept C11268172 @default.
- W2090581919 hasConcept C113196181 @default.
- W2090581919 hasConcept C121332964 @default.
- W2090581919 hasConcept C145148216 @default.
- W2090581919 hasConcept C147789679 @default.
- W2090581919 hasConcept C148898269 @default.
- W2090581919 hasConcept C178790620 @default.
- W2090581919 hasConcept C179104552 @default.
- W2090581919 hasConcept C184651966 @default.
- W2090581919 hasConcept C185592680 @default.
- W2090581919 hasConcept C2777064678 @default.
- W2090581919 hasConcept C2778237882 @default.
- W2090581919 hasConcept C2781014771 @default.
- W2090581919 hasConcept C43617362 @default.
- W2090581919 hasConcept C55493867 @default.
- W2090581919 hasConcept C58226133 @default.
- W2090581919 hasConcept C62520636 @default.
- W2090581919 hasConcept C93391505 @default.
- W2090581919 hasConceptScore W2090581919C102931765 @default.
- W2090581919 hasConceptScore W2090581919C11268172 @default.
- W2090581919 hasConceptScore W2090581919C113196181 @default.
- W2090581919 hasConceptScore W2090581919C121332964 @default.
- W2090581919 hasConceptScore W2090581919C145148216 @default.
- W2090581919 hasConceptScore W2090581919C147789679 @default.
- W2090581919 hasConceptScore W2090581919C148898269 @default.
- W2090581919 hasConceptScore W2090581919C178790620 @default.
- W2090581919 hasConceptScore W2090581919C179104552 @default.
- W2090581919 hasConceptScore W2090581919C184651966 @default.
- W2090581919 hasConceptScore W2090581919C185592680 @default.
- W2090581919 hasConceptScore W2090581919C2777064678 @default.
- W2090581919 hasConceptScore W2090581919C2778237882 @default.
- W2090581919 hasConceptScore W2090581919C2781014771 @default.
- W2090581919 hasConceptScore W2090581919C43617362 @default.
- W2090581919 hasConceptScore W2090581919C55493867 @default.
- W2090581919 hasConceptScore W2090581919C58226133 @default.
- W2090581919 hasConceptScore W2090581919C62520636 @default.
- W2090581919 hasConceptScore W2090581919C93391505 @default.
- W2090581919 hasIssue "2" @default.
- W2090581919 hasLocation W20905819191 @default.
- W2090581919 hasLocation W20905819192 @default.
- W2090581919 hasOpenAccess W2090581919 @default.
- W2090581919 hasPrimaryLocation W20905819191 @default.
- W2090581919 hasRelatedWork W1969883466 @default.
- W2090581919 hasRelatedWork W2017490885 @default.
- W2090581919 hasRelatedWork W2034827779 @default.
- W2090581919 hasRelatedWork W2038083942 @default.
- W2090581919 hasRelatedWork W2040146024 @default.
- W2090581919 hasRelatedWork W2052472050 @default.
- W2090581919 hasRelatedWork W2057996321 @default.
- W2090581919 hasRelatedWork W2082436628 @default.
- W2090581919 hasRelatedWork W2521159955 @default.
- W2090581919 hasRelatedWork W2952785262 @default.
- W2090581919 hasVolume "288" @default.
- W2090581919 isParatext "false" @default.
- W2090581919 isRetracted "false" @default.
- W2090581919 magId "2090581919" @default.
- W2090581919 workType "article" @default.