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• W2090582465 abstract "Adducts Snhal·pyz (hal = Cl, Br, I; pyz = pyrazine), RnSnCl4−n·pyz (n = 1, R = Me, Bun, Octn, Ph; n = 2, R = Ph) and SnCl4·(pyz)2 have been investigated by X-ray photoelectron spectroscopy. Binding energy (b.e.) values are discussed in the light of structural characteristics of the adducts as well as of valence state electronegativities of atoms and groups bound to tin. Sn 3d52 b.e.s, corrected for the Madelung potential at the metal atom, linearly correlate with both partial atomic charges on tin, accounting for relaxation upon ionization, and 119Sn Mössbauer isomer shifts. The results are interpreted in terms of six-coordinated, octahedral type, configurations of the environment of tin throughout all terms of the homologous series." @default.
• W2090582465 created "2016-06-24" @default.
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• W2090582465 date "1981-01-01" @default.
• W2090582465 modified "2023-10-14" @default.
• W2090582465 title "Relationship between XPS core binding energies and atomic charge in adducts of SnIV derivatives with pyrazine, and comparison with mössbauer isomer shift data" @default.
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• W2090582465 doi "https://doi.org/10.1016/s0020-1693(00)88566-7" @default.
• W2090582465 hasPublicationYear "1981" @default.
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