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- W2090588503 abstract "Die Desulfurierung von Thionocarbonaten 3 mit Fe(CO)5 und Fe2(CO)9 gibt je nach Energiequelle unterschiedliche Reaktionsprodukte. Bei der thermischen Reaktion (105°C, Toluol) entstehen Tetracarbonyl(dioxolanyliden)eisen(0)-Komplexe 4 und Olefine 2. Durch Bestrahlung entsteht ebenfalls 4, außerdem werden Clusterverbindungen der Zusammensetzung Fe3(CO)9S(dioxolanyliden) (5) isoliert. Bei allen Reaktionen wird außerdem Fe3(CO)9S2 (6) gebildet. Eine Röntgenstrukturanalyse von 4j zeigte den Dioxolanyliden-Liganden in der axialen Position einer trigonalen Bipyramide. (Dioxolanyliden)eisen(0)-Verbindungen sind „Ylide mit inverser Bindungspolarisation”︁ (15). Desulfurization Reactions with Iron Carbonyl Compounds: Carbonyl(dioxolanylidene)iron Complexes from Thionocarbonates Desulfurizations of thionocarbonates 3 with Fe(CO)5 and Fe2(CO)9 yield tetracarbonyl(dioxolanylidene)iron(0) complexes 4 and olefins 2 under thermal conditions. Photochemical conditions lead to 4 and cluster compounds with the formula Fe3(CO)9S(dioxolanylidene) (5). In all reactions Fe3(CO)9S2 (6) was also isolated. The carbene complexes are characterized spectroscopically. An X-ray structure analysis of the tetracarbonyliron carbene complex 4j shows the dioxolanylidene ligand in the axial position of a distorted trigonal bipyramid. (Dioxolanylidene)iron(0) complexes are „ylides with inverse bond polarizations”︁ (15)." @default.
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- W2090588503 date "1982-05-01" @default.
- W2090588503 modified "2023-10-09" @default.
- W2090588503 title "Desulfurierungsreaktionen mit Eisencarbonyl‐Verbindungen: Carbonyl(dioxolanyliden)eisen‐Komplexe aus Thionocarbonaten" @default.
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- W2090588503 cites W1586518381 @default.
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- W2090588503 cites W1982912096 @default.
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- W2090588503 cites W2001498174 @default.
- W2090588503 cites W2005575251 @default.
- W2090588503 cites W2008844584 @default.
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- W2090588503 cites W2043208500 @default.
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- W2090588503 doi "https://doi.org/10.1002/cber.19821150513" @default.
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