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- W2090596931 abstract "The title compound, {[Ni(SO4)(C6H16N2)(H2O)2]·H2O} n , contains a Ni(II) atom that is coordinated nearly octa-hedrally by a chelating tetra-ethyl-enediamine (tmeda) ligand, two water mol-ecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfate anions act as μ2-bridging ligands leading to a chain structure of alternating NiO4N2 octa-hedra and SO4 tetra-hedra parallel to [001]. The polymeric chains are linked by O-H⋯O hydrogen bonds between coordinating water mol-ecules and sulfate anions to give double strands. There is a lattice water mol-ecule which is also involved in O-H⋯O hydrogen bonding between adjacent [Ni(SO4)(tmeda)(H2O)2] chains." @default.
- W2090596931 created "2016-06-24" @default.
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- W2090596931 date "2013-03-13" @default.
- W2090596931 modified "2023-10-12" @default.
- W2090596931 title "<i>catena</i>-Poly[[[diaqua(tetramethylethylenediamine-κ<sup>2</sup><i>N</i>,<i>N</i>′)nickel(II)]-μ-sulfato-κ<sup>2</sup><i>O</i>:<i>O</i>′] monohydrate]" @default.
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- W2090596931 doi "https://doi.org/10.1107/s1600536813006557" @default.
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