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- W2090597223 abstract "Die Silaolefine 1 und dazu isomeren Methylsilylene 2 sind getrennt existenzfähige Spezies, lassen sich in einer Argonmatrix aber über eine photochemisch induzierte 1,2-H-Wanderung leicht ineinander umwandeln. Bei thermischer Anregung in der Gasphase ist sowohl die Isomerisierung eines Silaolefins zum zugehörigen Silylen (1d → 2d) als auch eines Silylens zum entsprechenden Silen (2f → 1f) direkt spektroskopisch nachweisbar. Hetero-π-Systems, 9. About the Relationships between Silaethenes and Methylsilylenes Silaethenes 1 and the isomeric methylsilylenes 2 are separately existing species, but can readily be interconverted in an argon matrix via a photochemically induced 1,2-H shift. In case of the thermal excitation in the gas phase examples for both directions have been detected spectroscopically: the isomerisation of a silaolefin into the corresponding silylene (1d → 2d) and the formation of a silene from a silylene (2f → 1f)." @default.
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- W2090597223 date "1984-07-01" @default.
- W2090597223 modified "2023-10-03" @default.
- W2090597223 title "Hetero‐π‐Systeme, 9. Über die Beziehungen zwischen Silaethenen und Methylsilylenen" @default.
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- W2090597223 doi "https://doi.org/10.1002/cber.19841170709" @default.
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