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- W2090599128 abstract "In order to stabilize and identified intermediates in the photochemical formation of CrIII(SQ)3 (SQ = ortho-semiquinone radical-anion) out of Cr(CO)6 and ortho-quinones (o-Q), this reaction has been studied at lower temperatures (T < 230 K). For comparison, the same reaction was performed for the corresponding para-quinone (p-Q) ligands. Both quinone isomers gave Cr0(CO)5L (L = quinone) complexes, which were characterized by IR and UV/Vis spectroscopy. Warming the solution of Cr0(CO)5(o-Q) in the absence of CO afforded CrIII(SQ)3, with no evidence for any carbonyl-containing intermediate. This is explained in terms of a concerted mechanism involving chelate ring formation accompanied by electron transfer to the o-Q ligand." @default.
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- W2090599128 date "1989-01-01" @default.
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- W2090599128 title "Reexamination of the photochemical oxidative decarbonylation of Cr(CO)6 by ortho-quinones: Low-temperature photolysis of Cr(CO)6 with ortho- and para-quinone isomers" @default.
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- W2090599128 doi "https://doi.org/10.1016/0022-328x(89)85250-7" @default.
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