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- W2090614361 abstract "Metal-catalyzed transfer hydrogenation processes provide a widely-used alternative to direct hydrogenation processes of ketones. As part of an ongoing program, we report enantioselective C2-symmetric bis(phosphinite)–ruthenium(II) catalytic systems for the transfer hydrogenation of prochiral aromatic ketones. The new catalytic systems can readily be formed under in situ conditions from C2-symmetric chiral bis(phosphinite) ligands and [Ru(η6-p-cymene)(μ-Cl)Cl]2 in transfer hydrogenation reaction media. These chiral ruthenium catalytic systems serve as catalyst precursors for the asymmetric transfer hydrogenation of acetophenone derivatives in iso-PrOH and giving the corresponding optical active secondary alcohols up to 94% ee." @default.
- W2090614361 created "2016-06-24" @default.
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- W2090614361 date "2013-04-01" @default.
- W2090614361 modified "2023-09-25" @default.
- W2090614361 title "Screening of C2-symmetric chiral phosphinites as ligands for ruthenium(II)-catalyzed asymmetric transfer hydrogenation of prochiral aromatic ketones" @default.
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- W2090614361 doi "https://doi.org/10.1016/j.jorganchem.2013.01.012" @default.
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