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- W2090627713 abstract "Difluorobis(fluoroxy)methane, BDM, is an electrophilic fluorinating agent that is capable of affecting selective monofluorination of 1,3-dicarbonyls such as diketones and ketoesters with very high regioselectivity. For example, in highly acidic anhydrous HF (AHF) solvent, fluorination of methyl 3-oxopentanoate (MOP) with BDM provides methyl 2-fluoro-3-oxo-pentanoate (MFOP) with 100% conversion and 95% selectivity. In mixtures of HF and methanol, fluorination conversions and selectivity are markedly lower. In comparison, direct fluorination of MOP with dilute F 2 typically affords a fluorinated product that is less pure, being contaminated with radical fluorination byproducts that are difficult to separate. Fluorination of MOP with dilute mixtures of BDM and F 2 is generally more selective than using dilute F 2 alone." @default.
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- W2090627713 date "2003-04-15" @default.
- W2090627713 modified "2023-09-27" @default.
- W2090627713 title "Fluorination of Methyl 3-Oxopentanoate (MOP) Using Difluorobis(fluoroxy)methane, BDM." @default.
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- W2090627713 doi "https://doi.org/10.1002/chin.200315065" @default.
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