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- W2090652799 abstract "A method based on energy balance over the repeat unit is used for the calculation of the elastic modulus of linear polymer crystals. The result for polyethylene agrees with that of Treloar who used a statical analysis over the whole molecule. Both methods are much simpler than those of Shimanouchi and Miyazawa, the latter being based on the complete potential function for the polymer. Using force constants based on a Urey Bradley force field, the following values of modulus were found (all syndiotactic except PE) in GN/m2: PE, 299; PVC, 153; PVF, 212; PVA, 142; PAN, 236; PMMA, 63." @default.
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- W2090652799 date "1973-10-01" @default.
- W2090652799 modified "2023-10-09" @default.
- W2090652799 title "Elastic modulus of linear polymer crystals" @default.
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- W2090652799 doi "https://doi.org/10.1016/0032-3861(73)90156-0" @default.
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