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- W2090685644 abstract "Dibenzohomobarrelen (4) wurde synthetisiert. Durch direkte Anregung mit Licht erhält man über eine Aryl-Aryl-Bindung ein Di-π-methan-Umlagerungsprodukt 5 und das Fluoren 6, das vermutlich über das Carben 11 gebildet wurde. Bei der Bestrahlung von partiell deuteriertem 4 wurde ein Deuteriumeffekt kH/kD = 4.8 bei der Bildung von 6 beobachtet. Photochemical Isomerization of Dibenzohomobarrelene Dibenzohomobarrelene (4) was synthesized. Direct irradiation forms through aryl-aryl bridging the di-π-methan rearrangement product 5 and the fluorene 6 which might be formed via the carbene 11. A deuterium effect kH/kD = 4.8 was observed in the formation of 6 when partially deuterated 4 was irradiated." @default.
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- W2090685644 date "1977-04-01" @default.
- W2090685644 modified "2023-09-27" @default.
- W2090685644 title "Photochemische Isomerisierung von Dibenzohomobarrelen" @default.
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- W2090685644 doi "https://doi.org/10.1002/cber.19771100441" @default.
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