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- W2090699193 abstract "The solvatochromic conformational transformation of electroconductive poly[3-(10-hydroxydecyl)]thiophene in dimethylpropyleneurea solution, due to the addition of poor solvent, was investigated. A red shift of 80 nm in the ultraviolet—visible absorption maximum suggests a much more extended conjugated π-system for the new conformation. The time scale of this change allows a spectrokinetic analysis as a function of the type and amount of poor solvent. Second-order reaction kinetics are evident in all cases, and this is interpreted within the framework of an intrachain rearrangement leading to a higher coplanarity of thiophene rings in the new phase. A solid phase, laid down at very long times, gives insight about the final steps of an association process." @default.
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- W2090699193 date "1996-11-01" @default.
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- W2090699193 title "Solvatochromism in poly[3-(10-hydroxydecyl)]thiophene: a spectrokinetic study of the conformational transition" @default.
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- W2090699193 doi "https://doi.org/10.1016/s0032-3861(96)00362-x" @default.
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