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• W2090726683 abstract "Commercial nitinol wire is oxidised at 480–530 °C/10 min in air. Surface morphology and chemistry is studied in detail using scanning electron microscopy, energy dispersive spectrometry, X-ray diffraction, Raman spectrometry and X-ray photoelectron spectroscopy. It is found that the main oxidation product at both temperatures is rutile containing a few at.% Ni. Beneath the rutile layer, there are titanium sub-oxides, showing characteristic maxima in depth profiles. Nickel in an oxidised state is present on the surface, whereas in a sub-surface region of scales, there is only metallic nickel. Thickness of the total oxide layers is 70 and 140 nm after oxidation at 480 and 530 °C, respectively. The preferential oxidation of titanium causes the formation of a Ni-enriched and Ti-depleted zone, suggesting the presence of Ni3Ti phase. XRD reveals that the presence of cubic B2 NiTi phase in the base alloy is not affected by oxidation at 480–530 °C/10 min." @default.
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• W2090726683 date "2008-07-01" @default.
• W2090726683 modified "2023-10-18" @default.
• W2090726683 title "Influence of a controlled oxidation at moderate temperatures on the surface chemistry of nitinol wire" @default.
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• W2090726683 doi "https://doi.org/10.1016/j.apsusc.2008.03.014" @default.
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