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- W2090752495 abstract "Bimetallic PdIn catalysts have been investigated for methanol steam reforming within a microstructured reactor. The catalytic activity and CO2 selectivity were found to be markedly dependent on the Pd:In ratio as well as on metal loading. The high CO2 selectivity of Pd–In/Al2O3 catalysts has been ascribed to the PdIn alloy formation, whereas the metallic Pd without contact with indium is responsible for CO selectivity. The initial start-up properties of the Pd–In/Al2O3 catalyst were significantly improved in comparison with Pd/ZnO catalyst, allowing for a rapid attainment of the steady state. These findings illustrate that the catalyst surface dynamically changes depending on the reaction environment and undergoes a self-optimization induced by the reactants, and consequently the pre-reduction at elevated temperature is not necessary to achieve high CO2 selectivity." @default.
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- W2090752495 date "2010-05-31" @default.
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- W2090752495 title "Methanol steam reforming over bimetallic Pd–In/Al2O3 catalysts in a microstructured reactor" @default.
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- W2090752495 doi "https://doi.org/10.1016/j.apcata.2010.03.004" @default.
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