Matches in SemOpenAlex for { <https://semopenalex.org/work/W2090768596> ?p ?o ?g. }
- W2090768596 endingPage "94" @default.
- W2090768596 startingPage "86" @default.
- W2090768596 abstract "The effect of several p-substituent groups (–F, –CH3, –OH, –COOH, –NHCOCH3) on the performances and the stability of aromatic monolayers on copper has been studied. All the results agreed indicating that such aromatic films are very stable and effective as corrosion inhibitors even in harsh conditions (aerated H2SO4 0.5 M). Nevertheless, while XP spectroscopy showed an excellent chemical stability for all the layers regardless the terminal groups, EIS measurements highlighted notably different protective properties and durability for the various SAMs. Such passivation depends not only on the hydrophobicity of the terminal group but, surprisingly, also on the electronic effect of the substituent on the ring as well. In particular, molecules having an electron-withdrawing substituent showed good passivity at first, a steep increase of their protective properties following the exposure to the electrolyte but a relatively poor stability. The presence of an electron-donating substituent, on the other hand, led to relatively poor initial protection, a slow reorganization but an exceptionally long durability." @default.
- W2090768596 created "2016-06-24" @default.
- W2090768596 creator A5002830953 @default.
- W2090768596 creator A5023478549 @default.
- W2090768596 creator A5038554988 @default.
- W2090768596 creator A5056863530 @default.
- W2090768596 date "2013-03-01" @default.
- W2090768596 modified "2023-10-18" @default.
- W2090768596 title "Effect of various terminal groups on long-term protective properties of aromatic SAMs on copper in acidic environment" @default.
- W2090768596 cites W1964156017 @default.
- W2090768596 cites W1968387786 @default.
- W2090768596 cites W1971221493 @default.
- W2090768596 cites W1971388536 @default.
- W2090768596 cites W1971942656 @default.
- W2090768596 cites W1973944021 @default.
- W2090768596 cites W1973950233 @default.
- W2090768596 cites W1975088941 @default.
- W2090768596 cites W1983271632 @default.
- W2090768596 cites W1986599588 @default.
- W2090768596 cites W1992214743 @default.
- W2090768596 cites W1993075903 @default.
- W2090768596 cites W1997619422 @default.
- W2090768596 cites W2000684861 @default.
- W2090768596 cites W2000935290 @default.
- W2090768596 cites W2001769045 @default.
- W2090768596 cites W2002152178 @default.
- W2090768596 cites W2006271726 @default.
- W2090768596 cites W2009017073 @default.
- W2090768596 cites W2009320832 @default.
- W2090768596 cites W2012286271 @default.
- W2090768596 cites W2020585602 @default.
- W2090768596 cites W2023082827 @default.
- W2090768596 cites W2023146483 @default.
- W2090768596 cites W2024330717 @default.
- W2090768596 cites W2026980839 @default.
- W2090768596 cites W2030634530 @default.
- W2090768596 cites W2036463959 @default.
- W2090768596 cites W2037163327 @default.
- W2090768596 cites W2041250639 @default.
- W2090768596 cites W2045006932 @default.
- W2090768596 cites W2045044725 @default.
- W2090768596 cites W2046016779 @default.
- W2090768596 cites W2048391619 @default.
- W2090768596 cites W2048599132 @default.
- W2090768596 cites W2048740940 @default.
- W2090768596 cites W2052041609 @default.
- W2090768596 cites W2054078392 @default.
- W2090768596 cites W2055927528 @default.
- W2090768596 cites W2056901120 @default.
- W2090768596 cites W2058855533 @default.
- W2090768596 cites W2064625801 @default.
- W2090768596 cites W2068426959 @default.
- W2090768596 cites W2068602023 @default.
- W2090768596 cites W2069838758 @default.
- W2090768596 cites W2077220250 @default.
- W2090768596 cites W2077228161 @default.
- W2090768596 cites W2083783900 @default.
- W2090768596 cites W2085440830 @default.
- W2090768596 cites W2090673599 @default.
- W2090768596 cites W2092813418 @default.
- W2090768596 cites W2094536176 @default.
- W2090768596 cites W2111482051 @default.
- W2090768596 cites W2120669000 @default.
- W2090768596 cites W2129363674 @default.
- W2090768596 cites W2141982227 @default.
- W2090768596 cites W2166806803 @default.
- W2090768596 cites W2319434464 @default.
- W2090768596 cites W2496653890 @default.
- W2090768596 cites W3024041711 @default.
- W2090768596 cites W35692615 @default.
- W2090768596 cites W4238069714 @default.
- W2090768596 doi "https://doi.org/10.1016/j.jelechem.2013.01.025" @default.
- W2090768596 hasPublicationYear "2013" @default.
- W2090768596 type Work @default.
- W2090768596 sameAs 2090768596 @default.
- W2090768596 citedByCount "19" @default.
- W2090768596 countsByYear W20907685962013 @default.
- W2090768596 countsByYear W20907685962014 @default.
- W2090768596 countsByYear W20907685962015 @default.
- W2090768596 countsByYear W20907685962016 @default.
- W2090768596 countsByYear W20907685962018 @default.
- W2090768596 countsByYear W20907685962019 @default.
- W2090768596 countsByYear W20907685962021 @default.
- W2090768596 countsByYear W20907685962022 @default.
- W2090768596 crossrefType "journal-article" @default.
- W2090768596 hasAuthorship W2090768596A5002830953 @default.
- W2090768596 hasAuthorship W2090768596A5023478549 @default.
- W2090768596 hasAuthorship W2090768596A5038554988 @default.
- W2090768596 hasAuthorship W2090768596A5056863530 @default.
- W2090768596 hasConcept C147789679 @default.
- W2090768596 hasConcept C17525397 @default.
- W2090768596 hasConcept C178790620 @default.
- W2090768596 hasConcept C179104552 @default.
- W2090768596 hasConcept C185592680 @default.
- W2090768596 hasConcept C2778689049 @default.
- W2090768596 hasConcept C2779227376 @default.
- W2090768596 hasConcept C33574316 @default.
- W2090768596 hasConcept C35396096 @default.