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- W2090782126 abstract "Two new optically active phosphines, 3α-diphenylphosphino-5α-cholestane [(+)-DICOL] and 2,3-O-(5′α-cholestan-3′,3′-ylidene)-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane [(−)-DIOCOL] have been prepared and used as ligands in transition metal catalyzed asymmetric processes. In CO-insertion reactions, especially in the Pd promoted hydrocarbalkoxylation,(+)-DICOL-based complexes displayed a remarkable catalytic activity and a very high regioselectivity, but a poor stereoselectivity. Optical yields of up to 93% and up to 34%, respectively, were obtained in asymmetric hydrogenation and hydroformylation catalyzed by rhodium complexes with (−)-DIOCOL." @default.
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- W2090782126 date "1983-03-01" @default.
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- W2090782126 title "Asymmetric hydrogenation, hydroformylation and hydrocarbalkoxylation of olefins by transition metal complexes with steroidal phosphines" @default.
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- W2090782126 doi "https://doi.org/10.1016/s0022-328x(00)98621-2" @default.
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