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- W2090784862 abstract "Abstract A series of samples of linear aromatic polyester of 3-phenylglutaric acid and bisphenol A was prepared with molecular weights ranging from 14 700 to 92 700. The polymers were characterized by size exclusion chromatography with triple light-scattering, viscosity, and concentration detection. Hydrodynamic parameters of the chain were determined using the theory of Yoshizaki, Yamakawa, and Nitta modified by Bohdanecký and Netopilík. The chain parameters are a useful reference in the study of aromatic hyperbranched polyesters. Keywords: Chain parametersLinear polyesterSize exclusion chromatographyTriple detection The authors gratefully acknowledge the donation of the DAWN laser photometer by Wyatt Technologies Ltd. and the support by the Academy of Sciences of the Czech Republic (projects nos. AVOZ 40500505 and A400500703) and the Czech Science Foundation (project no. 203/07/0659). The authors are deeply grateful to Dieter Voigt for fruitful discussions. Notes a The codes of the samples express the time of polymerization in hours. a Parameters of Equation (6). b Projection of monomer repeating unit on the chain axis with all bonds in trans conformation. c Ratio of the mean-square end-to-end distance in the random-coil limit and molecular weight. d Length of a segment of the equivalent chain. e Molecular weight per segment of the equivalent chain. f Reduced bead diameter. g Bead diameter. h Characteristic ratio." @default.
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- W2090784862 date "2007-06-28" @default.
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- W2090784862 title "Hydrodynamic Parameters of Linear Aromatic Polyester of 3-Phenylglutaric Acid and Bisphenol A" @default.
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- W2090784862 doi "https://doi.org/10.1080/10236660701385912" @default.
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