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• W2090801431 abstract "The physical properties and redox chemistry of perovskite-type LaCoO3 prepared by reactive grinding and by the citrate method, have been comparatively studied by temperature-programmed reduction (TPR), X-ray diffraction (XRD), N2 adsorption–desorption, and infrared spectroscopy (IR). XRD and N2 adsorption–desorption measurements show that LaCoO3 prepared by reactive grinding possesses a smaller particle size and thus a greater specific surface area. An IR study suggests that there would exist a large amount of oxygen defects in LaCoO3 prepared by reactive grinding. TPR results illustrate that the reduction of LaCoO3 to Co0/La2O3 requires a higher temperature for a sample prepared by reactive grinding than for the one prepared by the citrate method. Due to a more difficult reduction, LaCoO3 prepared by reactive grinding displays a better stability of the perovskite structure than LaCoO3 prepared by the citrate method under a reducing atmosphere." @default.
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• W2090801431 date "2005-08-01" @default.
• W2090801431 modified "2023-09-26" @default.
• W2090801431 title "Comparative Studies on the Properties of New and Conventional Perovskite-Type LaCoO3" @default.
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• W2090801431 doi "https://doi.org/10.1246/bcsj.78.1450" @default.
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