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- W2090836652 abstract "13C and proton NMR spectra of several arylpalladium and some arylnickel and arylplatinum complexes have been compared. The Ni(PEt3)2X and Pd(PEt3)2X substituents induce a paramagnetic shift of Cipso (of the phenyl ring) which is much larger than that induced by Pt(PEt3)2X. However, there are no significant differences along the Ni/Pd/Pt series for the ortho, meta and para positions. For the six compounds of general formula trans-[ArPdBr(PEt3)2] reported here, the mean Δ(δ)C values induced on the ArH by the introduction of the PdBr(PEt3)2 substituent are found to be 26.9 (Cipso), 7.2 (Cortho), −1.1 (Cmeta), −5.5 (Cpara), −0.03 (Hortho), −0.28 (Hmeta) and −0.38 ppm (Hpara)." @default.
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- W2090836652 date "1986-03-01" @default.
- W2090836652 modified "2023-09-24" @default.
- W2090836652 title "13C and proton nuclear magnetic resonance spectra oftrans-[arylbromobis(triethyl phosphine)palladium(II)] and related compounds. The π-donor ability of the Ni(PEt3)2X, Pd(PEt3)2X and Pt(PEt3)2X groups" @default.
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- W2090836652 doi "https://doi.org/10.1002/mrc.1260240311" @default.
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