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- W2090852399 abstract "The etheno bridge of a thevinone was treated with BH3 and H2O2 to give both the 18- and 19-hydroxyl- substituted thevinols. Selective benzylation of the primary 20-hydroxyl over the 19-hydroxyl was successful; however, benzylation of the 18-hydroxylated product led to a reaction at the more hindered alcohol. Thus, the 6,14-bridge of the Diels-Alder products of thebaine can be hydroxylated, which opens up these positions for further chemical manipulation." @default.
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- W2090852399 date "2005-01-27" @default.
- W2090852399 modified "2023-10-12" @default.
- W2090852399 title "Functionalization of the 6,14-Bridge of the Orvinols. 2.<sup>1</sup> Preparation of 18- and 19-Hydroxyl-Substituted Thevinols and Their Treatment with Benzyl Bromide" @default.
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- W2090852399 doi "https://doi.org/10.1021/jo048388u" @default.
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