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• W2090873893 endingPage "1021" @default.
• W2090873893 startingPage "1015" @default.
• W2090873893 abstract "The transformation mechanisms of thiourea in ethylene glycol solution was systematically investigated in this report, which shows the transformation process is influenced by the anion (NO3−, Cl−, Br−) and polyvinylpyrrolidone (PVP). Thiourea (tu) isomerizes into ammonium thiocyanate when NO3− is present, regardless of the existence of PVP. For Cl−, thiourea coordinates with copper anion to form [Cu(tu)]Cl·1/2H2O complex whether PVP is present. When it comes to Br−, thiourea hydrolyzes in the cooperation of PVP or coordinates with copper anion to form [Cu(tu)Br]·1/2H2O complex without PVP. The different transformation routes will lead to different phase evolution of the CuS system. This work may provide a new understanding of the transformation of thiourea in ethylene glycol solution. The optical properties of the as-prepared copper sulfides exhibit signi?cant stoichiometry-dependent features which may have potential applications in semiconductor photovoltaic devices." @default.
• W2090873893 created "2016-06-24" @default.
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• W2090873893 date "2013-07-19" @default.
• W2090873893 modified "2023-10-16" @default.
• W2090873893 title "Phase Evolution of CuS System in Ethylene Glycol Solution: the Effect of Anion and PVP on the Transformation of Thiourea" @default.
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• W2090873893 doi "https://doi.org/10.1002/cjoc.201300200" @default.
• W2090873893 hasPublicationYear "2013" @default.
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