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- W2090901193 abstract "The electrical resistivity of the high quality single crystals of one-dimensional bis(1,2-benzoquinonedioximato)platinum(II), Pt(bqd)2, has been studied at low temperatures and high pressures under hydrostatic conditions. The resistivity along the c-axis abruptly decreases with increasing pressure up to 0.9 GPa at room temperature. Pt(bqd)2 with an energy gap of about 0.3 eV at ambient pressure indicates the insulator-to-metal (IM) transition at around 0.8 GPa. The x-ray diffraction and the electronic spectrum of Pt(bqd)2 have been studied at room temperature and high pressures. The mechanism of the IM transition of Pt(bqd)2 is discussed. Below 235 K the resistivity of Pt(bqd)2 increases with decreasing temperature at around 0.8 GPa. The metal-to-insulator (MI) transition for Pt(bqd)2 is found at around 235 K under 0.8 GPa. This is the first example that the one-dimensional metal formed from single molecules shows the MI transition at low temperatures." @default.
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- W2090901193 date "2000-07-11" @default.
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- W2090901193 title "Metal to insulator transition of one-dimensional bis(1,2-benzoquinonedioximato)-platinum(II), Pt(bqd)<sub>2</sub>, at low temperatures and high pressures" @default.
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- W2090901193 doi "https://doi.org/10.1088/0953-8984/12/30/101" @default.
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