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- W2090903063 abstract "This work considers the ability of hydrogen fluoride (HF) to solvate excess electrons located on cyclic hydrocarbon surfaces. The principle applied involves the formation of systems in which excess electrons can be stabilized not only on concentrated molecular surface charge pockets but also by HF. Recent studies have shown that OH groups can form stable hydrogen-bonded networks on one side of a hydrocarbon surface (i.e. cyclohexane sheets), at the same time, the hydrogen atoms on the opposite side of this surface form a pocket of positive charge can attract the excess electron. This density can be further stabilized by the addition of an HF molecule that can form an 'anion with an internally solvated electron' (AISE) state. These systems are shown to be stable with respect to vertical electron detachment (VDE)." @default.
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- W2090903063 date "2007-01-01" @default.
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- W2090903063 title "Solvation of excess electrons trapped in charge pockets on molecular surfaces" @default.
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- W2090903063 doi "https://doi.org/10.1080/00268970601142632" @default.
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