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- W2090908513 abstract "For the preparation of the title compound, 9,10-dilithiumanthracene is treated with p-anisylchlorosilane to give 9,10-bis(p-anisylsily)anthracene (1) with high yields. The protodearylation of 1 with two equivalents of trific acid affords 9,10-bis(trifluoromethanesulfonatosily)anthracene, which can be converted into 9,10-disilylanthracene (2) using LiAlHP4. The crystal structures of 1 and 2 have been determined by single-crystal X-ray diffraction. Solutions of 1 and 2 in common organic solvents show a violet fluorescence. The fluorescence spectra are compared with data on anthracene and 9,10-disubstituted derivatives." @default.
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- W2090908513 date "1996-02-01" @default.
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- W2090908513 title "9,10-Disilylanthracene; synthesis, structure and fluorescence" @default.
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- W2090908513 doi "https://doi.org/10.1016/0022-328x(95)05789-r" @default.
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