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- W2090915612 abstract "Abstract The ratio of selenium to silver in α-Ag 2 Se between 200 and 320°C has been determined as a function of the silver activity in the selenide with the help of electrochemical measurements. The significance of the results for the quantitative interpretation of the disorder of electrons in α-Ag 2 Se and epecially their degeneracy is discussed. Because of the high disorder of the silver ions, a change of the chemical potential of silver by a change of the stoichiometric constitution is only given by a change of concentration of the quasi-free electrons, or of defect electrons. Analysis of the experimental data shows that the effective mass of the conduction-band electrons increases with increasing electron energy and also increases with excess silver content. The energetic band gap in the selenide is at least 0.1 eV." @default.
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- W2090915612 date "1982-02-01" @default.
- W2090915612 modified "2023-09-25" @default.
- W2090915612 title "Electrochemical investigation of electron disorder in α-Ag2Se" @default.
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- W2090915612 doi "https://doi.org/10.1016/0022-0728(82)87011-3" @default.
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