FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2090918480> ?p ?o ?g. }

• W2090918480 abstract "Abstract. The speciation of iodine in atmospheric aerosol is currently poorly understood. Models predict negligible iodide concentrations and accumulation of iodate in aerosol, both of which is not confirmed by recent measurements. We present an updated aqueous phase iodine chemistry scheme for use in atmospheric chemistry models and discuss sensitivity studies with the marine boundary layer model MISTRA. These studies show that iodate can be reduced in acidic aerosol by inorganic reactions, i.e., iodate does not necessarily accumulate in particles. Furthermore, the transformation of particulate iodide to volatile iodine species likely has been overestimated in previous model studies due to negligence of collision-induced upper limits for the reaction rates. However, inorganic reaction cycles still do not seem to be sufficient to reproduce the observed range of iodide – iodate speciation in atmospheric aerosol. Therefore, we also investigate the effects of the recently suggested reaction of HOI with dissolved organic matter to produce iodide. If this reaction is fast enough to compete with the inorganic mechanism, it would not only directly lead to enhanced iodide concentrations but, indirectly via speed-up of the inorganic iodate reduction cycles, also to a decrease in iodate concentrations. Hence, according to our model studies, organic iodine chemistry, combined with inorganic reaction cycles, is able to reproduce observations. The presented chemistry cycles are highly dependent on pH and thus offer an explanation for the large observed variability of the iodide – iodate speciation in atmospheric aerosol." @default.
• W2090918480 created "2016-06-24" @default.
• W2090918480 creator A5002433047 @default.
• W2090918480 creator A5075995207 @default.
• W2090918480 creator A5089483906 @default.
• W2090918480 date "2006-11-03" @default.
• W2090918480 modified "2023-10-17" @default.
• W2090918480 title "Modeling iodide – iodate speciation in atmospheric aerosol" @default.
• W2090918480 cites W1504665535 @default.
• W2090918480 cites W1541128914 @default.
• W2090918480 cites W1966722452 @default.
• W2090918480 cites W1970805937 @default.
• W2090918480 cites W1974335431 @default.
• W2090918480 cites W1977695012 @default.
• W2090918480 cites W2002610056 @default.
• W2090918480 cites W2012763088 @default.
• W2090918480 cites W2014332519 @default.
• W2090918480 cites W2017636650 @default.
• W2090918480 cites W2028714024 @default.
• W2090918480 cites W2031964486 @default.
• W2090918480 cites W2035244950 @default.
• W2090918480 cites W2039515110 @default.
• W2090918480 cites W2043575608 @default.
• W2090918480 cites W2043669062 @default.
• W2090918480 cites W2044229641 @default.
• W2090918480 cites W2046582747 @default.
• W2090918480 cites W2060355323 @default.
• W2090918480 cites W2060499087 @default.
• W2090918480 cites W2061670598 @default.
• W2090918480 cites W2061847403 @default.
• W2090918480 cites W2069731196 @default.
• W2090918480 cites W2075047905 @default.
• W2090918480 cites W2078882371 @default.
• W2090918480 cites W2089964476 @default.
• W2090918480 cites W2093662671 @default.
• W2090918480 cites W2101077134 @default.
• W2090918480 cites W2103160221 @default.
• W2090918480 cites W2109656075 @default.
• W2090918480 cites W2130226454 @default.
• W2090918480 cites W2131793179 @default.
• W2090918480 cites W2142436371 @default.
• W2090918480 cites W2151976878 @default.
• W2090918480 cites W2160201336 @default.
• W2090918480 cites W2161144418 @default.
• W2090918480 cites W2230007037 @default.
• W2090918480 cites W2316684534 @default.
• W2090918480 cites W2327192955 @default.
• W2090918480 cites W2489077802 @default.
• W2090918480 cites W2952407937 @default.
• W2090918480 doi "https://doi.org/10.5194/acpd-6-10959-2006" @default.
• W2090918480 hasPublicationYear "2006" @default.
• W2090918480 type Work @default.
• W2090918480 sameAs 2090918480 @default.
• W2090918480 citedByCount "2" @default.
• W2090918480 crossrefType "posted-content" @default.
• W2090918480 hasAuthorship W2090918480A5002433047 @default.
• W2090918480 hasAuthorship W2090918480A5075995207 @default.
• W2090918480 hasAuthorship W2090918480A5089483906 @default.
• W2090918480 hasBestOaLocation W20909184801 @default.
• W2090918480 hasConcept C107872376 @default.
• W2090918480 hasConcept C178790620 @default.
• W2090918480 hasConcept C179104552 @default.
• W2090918480 hasConcept C185592680 @default.
• W2090918480 hasConcept C2776838516 @default.
• W2090918480 hasConcept C2778870691 @default.
• W2090918480 hasConcept C2779345167 @default.
• W2090918480 hasConcept C2780284529 @default.
• W2090918480 hasConcept C49999975 @default.
• W2090918480 hasConcept C508106653 @default.
• W2090918480 hasConcept C539932907 @default.
• W2090918480 hasConcept C78458016 @default.
• W2090918480 hasConcept C86803240 @default.
• W2090918480 hasConceptScore W2090918480C107872376 @default.
• W2090918480 hasConceptScore W2090918480C178790620 @default.
• W2090918480 hasConceptScore W2090918480C179104552 @default.
• W2090918480 hasConceptScore W2090918480C185592680 @default.
• W2090918480 hasConceptScore W2090918480C2776838516 @default.
• W2090918480 hasConceptScore W2090918480C2778870691 @default.
• W2090918480 hasConceptScore W2090918480C2779345167 @default.
• W2090918480 hasConceptScore W2090918480C2780284529 @default.
• W2090918480 hasConceptScore W2090918480C49999975 @default.
• W2090918480 hasConceptScore W2090918480C508106653 @default.
• W2090918480 hasConceptScore W2090918480C539932907 @default.
• W2090918480 hasConceptScore W2090918480C78458016 @default.
• W2090918480 hasConceptScore W2090918480C86803240 @default.
• W2090918480 hasLocation W20909184801 @default.
• W2090918480 hasLocation W20909184802 @default.
• W2090918480 hasLocation W20909184803 @default.
• W2090918480 hasLocation W20909184804 @default.
• W2090918480 hasLocation W20909184805 @default.
• W2090918480 hasLocation W20909184806 @default.
• W2090918480 hasOpenAccess W2090918480 @default.
• W2090918480 hasPrimaryLocation W20909184801 @default.
• W2090918480 hasRelatedWork W126352917 @default.
• W2090918480 hasRelatedWork W1964798571 @default.
• W2090918480 hasRelatedWork W1975218423 @default.
• W2090918480 hasRelatedWork W2078985763 @default.
• W2090918480 hasRelatedWork W2125981568 @default.
• W2090918480 hasRelatedWork W2338511669 @default.
• W2090918480 hasRelatedWork W2808214700 @default.

• next