SemOpenAlex |

SemOpenAlex

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2090921786> ?p ?o ?g. }

Showing items 1 to 100 of ±131 with 100 items per page.

W2090921786 endingPage "7740" @default.
W2090921786 startingPage "7735" @default.
W2090921786 abstract "Three p-tert-butylthiacalix[4]arene (H(4)TC4A)-supported Co(II) compounds, [Co(4)(TC4A)(N(3))(4)(N(6)H(2))(CH(3)OH)](CH(3)OH)(2) (1), [Co(8)(TC4A)(2)(N(3))(2)(N(6)H(2))(2)(CH(3)COO)(4)(CH(3)OH)(4)](OH)(2)(CH(3)OH)(4) (2), and [Co(10)(TC4A)(4)(N(3))(4)](CH(3)OH)(4) (3), have been solvothermally obtained in one pot and structurally characterized by single-crystal X-ray diffraction analyses, powder XRD, and IR spectroscopy. This work presents the first one-dimensional (1) cobalt cluster for the calixarene complexes and another two octanuclear (2) or decanuclear (3) cobalt clusters. In the structures of compounds 1 and 2, a novel N(6)H(2) ligand formed by the in situ (2 + 3) cycloaddition of two azides was observed. Density functional theory (DFT) calculations give the heat of formation (2N(3)(-) + 2H(+) --> N(6)H(2)) and decomposition energy (N(6)H(2) --> 3N(2) + H(2)) of 677.47 and 124.85 kcal/mol, respectively. Furthermore, an intergradation was determined at the B3LYP/6-311++g(d,p) level for the formation of the N(6)H(2) ligand. In addition, one TC4A ligand of a sandwich unit adopts a cone conformation, while the other adopts a pinched cone conformation in 3. The magnetic properties of these three compounds were influenced mainly by the orbital contributions of the distorted octahedral Co(II) ions." @default.
W2090921786 created "2016-06-24" @default.
W2090921786 creator A5007599353 @default.
W2090921786 creator A5029705815 @default.
W2090921786 creator A5032289331 @default.
W2090921786 creator A5039657597 @default.
W2090921786 creator A5051742417 @default.
W2090921786 creator A5059155432 @default.
W2090921786 creator A5082373596 @default.
W2090921786 creator A5083634613 @default.
W2090921786 date "2010-08-04" @default.
W2090921786 modified "2023-09-27" @default.
W2090921786 title "Three p-tert-Butylthiacalix[4]arene-Supported Cobalt Compounds Obtained in One Pot Involving In Situ Formation of N6H2 Ligand" @default.
W2090921786 cites W1530128299 @default.
W2090921786 cites W1566536395 @default.
W2090921786 cites W1966591337 @default.
W2090921786 cites W1968970022 @default.
W2090921786 cites W1969872919 @default.
W2090921786 cites W1971428917 @default.
W2090921786 cites W1973219115 @default.
W2090921786 cites W1979956099 @default.
W2090921786 cites W1999430010 @default.
W2090921786 cites W2009982263 @default.
W2090921786 cites W2013652476 @default.
W2090921786 cites W2015052072 @default.
W2090921786 cites W2023880573 @default.
W2090921786 cites W2024509898 @default.
W2090921786 cites W2025806133 @default.
W2090921786 cites W2027686003 @default.
W2090921786 cites W2029891039 @default.
W2090921786 cites W2037489433 @default.
W2090921786 cites W2054847317 @default.
W2090921786 cites W2055650374 @default.
W2090921786 cites W2059691051 @default.
W2090921786 cites W2060213036 @default.
W2090921786 cites W2073149497 @default.
W2090921786 cites W2074943034 @default.
W2090921786 cites W2076288658 @default.
W2090921786 cites W2096244632 @default.
W2090921786 cites W2096593854 @default.
W2090921786 cites W2099148507 @default.
W2090921786 cites W2113338846 @default.
W2090921786 cites W2127151516 @default.
W2090921786 cites W2131350133 @default.
W2090921786 cites W2135578814 @default.
W2090921786 cites W2143469496 @default.
W2090921786 cites W2145219686 @default.
W2090921786 cites W2146576260 @default.
W2090921786 cites W2152932169 @default.
W2090921786 cites W2156986703 @default.
W2090921786 cites W2157986221 @default.
W2090921786 cites W2160331868 @default.
W2090921786 cites W2164461525 @default.
W2090921786 cites W2165167119 @default.
W2090921786 cites W2332443737 @default.
W2090921786 cites W2949321721 @default.
W2090921786 cites W4210969260 @default.
W2090921786 cites W4210991126 @default.
W2090921786 cites W4236277458 @default.
W2090921786 cites W4253222887 @default.
W2090921786 doi "https://doi.org/10.1021/ic1005105" @default.
W2090921786 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20684511" @default.
W2090921786 hasPublicationYear "2010" @default.
W2090921786 type Work @default.
W2090921786 sameAs 2090921786 @default.
W2090921786 citedByCount "55" @default.
W2090921786 countsByYear W20909217862012 @default.
W2090921786 countsByYear W20909217862013 @default.
W2090921786 countsByYear W20909217862014 @default.
W2090921786 countsByYear W20909217862015 @default.
W2090921786 countsByYear W20909217862016 @default.
W2090921786 countsByYear W20909217862017 @default.
W2090921786 countsByYear W20909217862018 @default.
W2090921786 countsByYear W20909217862020 @default.
W2090921786 countsByYear W20909217862021 @default.
W2090921786 countsByYear W20909217862023 @default.
W2090921786 crossrefType "journal-article" @default.
W2090921786 hasAuthorship W2090921786A5007599353 @default.
W2090921786 hasAuthorship W2090921786A5029705815 @default.
W2090921786 hasAuthorship W2090921786A5032289331 @default.
W2090921786 hasAuthorship W2090921786A5039657597 @default.
W2090921786 hasAuthorship W2090921786A5051742417 @default.
W2090921786 hasAuthorship W2090921786A5059155432 @default.
W2090921786 hasAuthorship W2090921786A5082373596 @default.
W2090921786 hasAuthorship W2090921786A5083634613 @default.
W2090921786 hasConcept C115624301 @default.
W2090921786 hasConcept C116569031 @default.
W2090921786 hasConcept C147597530 @default.
W2090921786 hasConcept C152365726 @default.
W2090921786 hasConcept C170493617 @default.
W2090921786 hasConcept C179104552 @default.
W2090921786 hasConcept C185592680 @default.
W2090921786 hasConcept C198819137 @default.
W2090921786 hasConcept C515602321 @default.
W2090921786 hasConcept C55493867 @default.
W2090921786 hasConcept C71240020 @default.
W2090921786 hasConcept C8010536 @default.
W2090921786 hasConceptScore W2090921786C115624301 @default.