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- W2090935408 abstract "Abstract HCl‐Addition an 3‐Methoxy‐ o ‐chinon und nachfolgende Entmethylierung liefert 5‐Chlor‐pyrogallol, Benzolsulfinsäure‐Addition und anschließende Methylierung führt zum 2.3.4‐Trimethoxy‐diphenylsulfon. Thiophenol wird in 6‐Stellung eingelagert.–An das (nicht faßbare) Intermediärprodukt der Purpurogallinbildung aus Pyrogallol, das 3‐Hydroxy‐ o ‐chinon, wird Benzoisulfinsäure zu 3.4.5‐Trihydroxy‐diphenylsulfon addiert; dessen Permethylierungsprodukt wie auch das 2.3.4‐Trimethoxy‐Isomere werden zum Konstitutionsbeweis auf unabhängigen Wegen synthetisiert." @default.
- W2090935408 created "2016-06-24" @default.
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- W2090935408 date "1961-05-01" @default.
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- W2090935408 title "Zur Kenntnis der <i>o</i> ‐Chinone, XVI. Additionsreaktionen mit 3‐Methoxy‐ <i>o</i> ‐chinon" @default.
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- W2090935408 doi "https://doi.org/10.1002/cber.19610940516" @default.
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