FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2090936306> ?p ?o ?g. }

• W2090936306 endingPage "1004" @default.
• W2090936306 startingPage "996" @default.
• W2090936306 abstract "C60 bis-adduct containing a mixture of regio-isomers with different LUMO energy levels and steric geometries could greatly affect the morphological and bulk properties. To investigate the regio-isomer effect on solar cell performance, we have successfully designed and synthesized a regio-selective 4-acetatephenyl-4′-methylphenylmethano C60 bis-adduct (S-APM-CBA) by “tether-directed remote functionalization” strategy and a random 4-acetatephenyl-4′-methylphenylmethano C60 bis-adduct denoted as R-APM-CBA by traditional cyclopropanation. The dramatic reduction in the number of regio-isomers in S-APM-CBA is confirmed by the 1H NMR and HPLC measurements and theoretical calculation. Compared to the R-APM-CBA-based device with a Jsc of 6.63 mA/cm2, an FF of 44.3% and a PCE of 2.46%, the device using S-APM-CBA yielded a much lower Jsc of 1.48 mA/cm2, an FF of 32.2%, and a PCE of 0.38%. Consistently, the electron-only device using S-AMP-CBA exhibited lower electron mobility than the R-AMP-CBA-based device. These results imply that the electronic shallow-trap effect ascribed to the LUMO energy variations turned out to be insignificant in the AMP-CBA system. The lower efficiency and mobility of S-AMP-CBA might due to the assumption that the most probable trans-4-III isomer in S-AMP-CBA prevents the intermolecular facial contact of fullerenes, thereby hindering the electron transporting. Furthermore, the nanomorphology of S-AMP-CBA and R-AMP-CBA active layers could be different because of their different three-dimensional structures. This research demonstrated that steric effect of regio-isomers in a given C60 bis-adduct is more crucial than electronic shallow-trap effect." @default.
• W2090936306 created "2016-06-24" @default.
• W2090936306 creator A5003809155 @default.
• W2090936306 creator A5006002662 @default.
• W2090936306 creator A5030744047 @default.
• W2090936306 creator A5033106526 @default.
• W2090936306 creator A5043812605 @default.
• W2090936306 creator A5068552194 @default.
• W2090936306 creator A5091533843 @default.
• W2090936306 date "2013-12-30" @default.
• W2090936306 modified "2023-09-23" @default.
• W2090936306 title "Reducing Regioisomers of Fullerene-Bisadducts by Tether-Directed Remote Functionalization: Investigation of Electronically and Sterically Isomeric Effects on Bulk-Heterojunction Solar Cells" @default.
• W2090936306 cites W1963520473 @default.
• W2090936306 cites W1979162682 @default.
• W2090936306 cites W1979470200 @default.
• W2090936306 cites W1980954971 @default.
• W2090936306 cites W1981807138 @default.
• W2090936306 cites W1998956853 @default.
• W2090936306 cites W2003350932 @default.
• W2090936306 cites W2006874950 @default.
• W2090936306 cites W2007405223 @default.
• W2090936306 cites W2018271271 @default.
• W2090936306 cites W2022832540 @default.
• W2090936306 cites W2024954708 @default.
• W2090936306 cites W2025366167 @default.
• W2090936306 cites W2029853450 @default.
• W2090936306 cites W2032600692 @default.
• W2090936306 cites W2036531934 @default.
• W2090936306 cites W2041118010 @default.
• W2090936306 cites W2047317486 @default.
• W2090936306 cites W2047951832 @default.
• W2090936306 cites W2055499045 @default.
• W2090936306 cites W2056369790 @default.
• W2090936306 cites W2058857635 @default.
• W2090936306 cites W2060750121 @default.
• W2090936306 cites W2063106858 @default.
• W2090936306 cites W2069690816 @default.
• W2090936306 cites W2071134066 @default.
• W2090936306 cites W2081997988 @default.
• W2090936306 cites W2086849811 @default.
• W2090936306 cites W2098677114 @default.
• W2090936306 cites W2100077118 @default.
• W2090936306 cites W2121154500 @default.
• W2090936306 cites W2124790005 @default.
• W2090936306 cites W2126031985 @default.
• W2090936306 cites W2130972704 @default.
• W2090936306 cites W2133899668 @default.
• W2090936306 cites W2144985121 @default.
• W2090936306 cites W2145598561 @default.
• W2090936306 cites W2153312496 @default.
• W2090936306 cites W2158118731 @default.
• W2090936306 cites W2170210838 @default.
• W2090936306 cites W2170609124 @default.
• W2090936306 cites W2318397719 @default.
• W2090936306 cites W2325950121 @default.
• W2090936306 cites W2951087539 @default.
• W2090936306 cites W2953203907 @default.
• W2090936306 doi "https://doi.org/10.1021/am404485t" @default.
• W2090936306 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24344911" @default.
• W2090936306 hasPublicationYear "2013" @default.
• W2090936306 type Work @default.
• W2090936306 sameAs 2090936306 @default.
• W2090936306 citedByCount "28" @default.
• W2090936306 countsByYear W20909363062014 @default.
• W2090936306 countsByYear W20909363062015 @default.
• W2090936306 countsByYear W20909363062016 @default.
• W2090936306 countsByYear W20909363062017 @default.
• W2090936306 countsByYear W20909363062018 @default.
• W2090936306 countsByYear W20909363062019 @default.
• W2090936306 countsByYear W20909363062021 @default.
• W2090936306 countsByYear W20909363062023 @default.
• W2090936306 crossrefType "journal-article" @default.
• W2090936306 hasAuthorship W2090936306A5003809155 @default.
• W2090936306 hasAuthorship W2090936306A5006002662 @default.
• W2090936306 hasAuthorship W2090936306A5030744047 @default.
• W2090936306 hasAuthorship W2090936306A5033106526 @default.
• W2090936306 hasAuthorship W2090936306A5043812605 @default.
• W2090936306 hasAuthorship W2090936306A5068552194 @default.
• W2090936306 hasAuthorship W2090936306A5091533843 @default.
• W2090936306 hasConcept C108204754 @default.
• W2090936306 hasConcept C115537861 @default.
• W2090936306 hasConcept C14158195 @default.
• W2090936306 hasConcept C147789679 @default.
• W2090936306 hasConcept C159985019 @default.
• W2090936306 hasConcept C162862793 @default.
• W2090936306 hasConcept C178790620 @default.
• W2090936306 hasConcept C185592680 @default.
• W2090936306 hasConcept C192562407 @default.
• W2090936306 hasConcept C201194858 @default.
• W2090936306 hasConcept C206991015 @default.
• W2090936306 hasConcept C32909587 @default.
• W2090936306 hasConcept C49040817 @default.
• W2090936306 hasConcept C521977710 @default.
• W2090936306 hasConcept C66187686 @default.
• W2090936306 hasConcept C71240020 @default.
• W2090936306 hasConcept C75473681 @default.
• W2090936306 hasConcept C91614233 @default.
• W2090936306 hasConceptScore W2090936306C108204754 @default.

• next